Marvel's Ultimate Spider-Man (2012)

S01E15 For Your Eye Only

Spider-Man arrives late to training and immediately confronts a formidable threat: a sinister super army known as Zodiac, led by Scorpio. Having seized control of the S.H.I.E.L.D. Helicarrier, Scorpio has activated its self-destruct sequence. To tackle this dire situation, Spider-Man and Nick Fury must set aside their disagreements and join forces to combat this new adversary together.