One Piece (1999)

S02E76 Time to Fight Back! Usopp’s Quick Thinking and Fire Star!

Usopp manages to free Luffy from the grip of Miss Goldenweek's influence. With Karoo lending a hand, they work together to save the rest of their crew, who then confront Mr. 5 and Miss Valentine. Meanwhile, Luffy and Karoo chase after Mr. 3 and Miss Goldenweek as they flee into the forest.